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Velocity
Modulation Spectrometer Block Diagram
Below is a block diagram of the velocity modulation
spectrometer.
The radiation source, detector, and phase-locking electronics are
similar to the low
temperature spectrometer. The main differences concern the reaction
chamber, optics, and detection scheme. The reaction chamber is a
methanol-cooled glass vacuum cell, which contains two ring discharge
electrodes. The optics scheme is a single-pass system with two lenses
on either end of the reaction cell. An AC discharge is created in the
glass cell to create molecular ions. The frequency of the AC
discharge is used to selectively detect these ions using a technique
known as velocity modulation.
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