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Spectra and Hamiltonians
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4Σ
For KC, the four spin-components of the quartet are well resolved.
For NaC, the middle two spin-components are not resolved; therefore, they appear as a more intense single feature.
For CrN, the four spin-components are asymmetrically spaced due to the large value of the spin-spin parameter, l.
A generalized energy level diagram for a molecule in a 4Σ state.
H(effective) = H(rotation) +
H(spin rotation) + H(3)(spin rotation) + H(spin spin)
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