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Metal methylidines

MCH X r0 MC (Å) r0 CH (Å) Reference
NaCH 3Σ- 2.207 1.073 Xin and Ziurys, JCP 110, 3360 (1999).
KCH 3Σ- 2.526 1.082 Xin and Ziurys, JCP 110, 3360 (1999).
TiCH 2Σ 1.7277(3) 1.085(2) *Barnes, Merer, and Metha, JMS 181, 168 (1996).
VCH 3Δr 1.7025 1.080 *Barnes, et. al., JACS 117, 2096 (1995).
WCH 2Δ3/2 1.0765 1.73665 *Barnes, et. al., JCP 105, 6168 (1996).

* Optical Spectroscopy