University of Arizona

Ziurys Group Observational Astrochemistry

Ziurys Group Links

Main Page
Observational Research
Laboratory Research
Meet the Ziurys Group
Group Publications
Ziurys Research Profile
Lucy Ziurys CV
University of Arizona
Chemistry Department
Physical Chemistry Group
Steward Observatory

Telescopes

ARO KP12 Meter
ARO SMT
IRAM 30 Meter


Measurements of Galactic 12C/13C
Isotope Ratios using CO and CN

            New measurements of 12C/13C ratios in galactic molecular clouds have been conducted using the N=1 --> 0 transition of the CN radical.  This species is unique in that it has extensive hyperfine structure that can be accurately used to correct for line saturation effects.  Combined with the past observations of Savage et al. (2002), the ratios derived from CN are the most extensive data set to date for molecular clouds and include sources that lie in the range of 0.09-16.41 kpc in distance from the Galactic center (DGC).  The ratios derived from CN indicate a gradient with Galactic distance of 12C/13C = 6.01 DGC + 12.28.  This gradient agrees relatively closely with those derived from millimeter measurements of CO and H2CO.  The average gradient determined from all three molecules is 12C/13C = 6.21 DGC + 18.71.  CO, CN and H2CO are synthesized from quite different reactions, and any 13C fractionation must follow different pathways for these three species.  The relatively good agreement between the 12C/13C ratios of the three molecules, as well as its lack of correlation with gas kinetic temperature, suggests that chemical fractionation does not play a substantial role in influencing such ratios.  Therefore, the 12C/13C gradient found in the Galaxy is a true indicator of Galactic chemical evolution.  The apparent discrepancy between the solar system (12C/13C = 89) and local interstellar medium values (12C/13C = 68) of this ratio may be a result of 13C enrichment since the formation of the solar system, as predicted by recent models.

Below, 12CN and 13CN spectra towards S156
showing a 12C/13C ratio of 78.

CN Isotopomers Spectra