Ziurys Group Rotational Spectroscopy Research

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Metal amides MNH2a X r0 MN (Å) r0 NH (Å) ΘHNH (°) Reference LiNH2 1A1 1.736(3) 1.022(3) 106.9(1) Grotjahn et. al., JACS 123, 5489 (2001). NaNH2 1A1 2.091(3) 1.008(3) 106.6(1) Grotjahn et. al., JACS 123, 5489 (2001). MgNH2 2A1 1.899(3) 1.007(3) 108.7(5) Sheridan and Ziurys, CJP 79, 409 (2001). CaNH2 2A1 2.126(3) 1.018(3) 105.8(5) Brewster and Ziurys, JCP 113, 3141 (2000). SrNH2 2A1 2.256(1) 1.021(1) 105.4(1) Thompsen, Sheridan and Ziurys, CPL 330, 373 (2000). a) Structures calculated from MND2 isotopic substitution.